[net.columbia] temperature effects on SRBs

kaplow@crvax1.DEC (Have you kicked your cat today?) (01/30/86)

	I'm still in a daze from yesterdays news. I have followed the space
    program from its beginnings and can't remember anything like this,
    including the Apollo 1 fire 19 years ago. 

	To answer the question, I have been involved in model rockets for
    over 20 years, and am very familiar with temperature induced problems in
    solid propellants. The black powder motors do suffer from temperature
    problems, occuring when the motor is fired at a colder temperature than
    it was stored at. This is usually the result of storing the motor at a
    very high temperature, like the trunk of a car on a hot summer day, but
    can also be caused by firing a motor on a cold day, as was the case in
    Florida yesterday. These motors are very different in design and
    construction from the SRBs. 

	Some of the new high power motors use almost exactly the same
    propellant, save a few trace additives, as the SRBs. They consist of
    about 15% rubber propellant (poly something or other) and 85% ammonium
    perchlorate oxidizer. These seem to be immune to any storage problems.
    The propellant itself is a rubber like material, thus temperature
    changes do not cause cracking or bond separation. Hard shock also has no
    effect on this material. Over a very long time, surface oxidation will
    cause some deterioration, but this requires an unsealed motor and
    several years to happen. 

	One of the advantages of this propellant is that it will not
    explode. Many solid propellants burn faster as chamber pressure
    increases, causing a chain reaction leading to an explosion. The AP
    propellant actually burns slower as pressure increases, regulating
    itself. In fact, these motors are often hard to ignite, needing to be
    rapidly pressurized or they will extinguish themselves. Any casing
    rupture usually extinguishes the propellant, or at least causes it to
    burn slowly without producing any thrust. Scraps of this propellant
    material will burn in an ash tray if lit with a match, but no more
    violently than a similar hunk of rubber. 

	These model rocket motors, like the SRBs are usually ported down the
    center, giving a large initial burn area. They burn radially out toward
    the casing, thus the unburnt propellant is the insulation that prevents
    the casing from burning thru. A void in the cast propellant, or a crack
    between the seperately cast segments in the motor, could cause one part
    of the motor to burn all of its propellant down to the metal wall sooner
    than the rest of the motor. There was some concern about this on a
    flight a year or so, which they found after recovering the spent SRB. 

	The first replay I saw of the disaster was on a 5" screen, and it
    looked like one of the SRBs might have burned thru and started the chain
    of events. Later replays last night show either a leak in the rear area
    of the ET, or around the 3 liquid engines, just after throttle up. Once
    this trail ignited, the whole ET went with it. The fact that the two
    SRBs continued burning while tumbling leads me to believe that the SRBs
    performed properly. I guess we will have to wait for NASA to analyze all
    of the data and find the cause, as the spokesman yesterday made it
    pretty clear that they were not going to give the media any more footage
    or information until the investigation is completed. 


    		Bob Kaplow 
    		Digital Equipment Corp. 
    		Arlington Heights, IL 

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