[sci.chem] Need information on Cu,Ni,Cr plating of 1m dia hemisphere

bwhite@oucsace.cs.ohiou.edu (Bill White ) (02/02/91)

	I apologize in advance for cross-posting, but I have asked questions
along this general theme before and gotten little or no response.  Please
direct all responses to me, or if you must follow up please do it in
sci.electronics.

	Essentially I am trying to form four (4) 1 meter hemispheres (with
a 10 degree "excess", making it slightly more than a hemisphere) for use
in a Van de Graaff system.  After investigating various technologies such
as spun aluminum and explosive forming, I found them either beyond my means
financially and/or beyond the abilities of our university.  It was suggested
I investigate electroplating.  Cost for custom-production of the four
hemispheres by traditional methods was quoted from $1000 up.  This is more
than I would like to pay.

	What I would like to do is take a form, 1 meter diameter, coat it
with a conductive material, plate a 1/8 to 1/4 inch (sorry about mixing
measurement units) thick layer of copper (yes I know that's awful thick),
do some elementary forming, and then coat it with nickel and then chromium.
The resulting finish *must* be smooth, though I don't really care what it
looks like.  The copper *must* be malleable, though if it can be annealed
to make it malleable that is fine as well.

	One idea that popped into my head was to use an aluminized mylar
spherical balloon, strike plate it in a cyanide plating solution, then
finish plating the copper in an acid solution.  Most of my metal plating
experience, however, has been with small items using only acid solutions.
If I can find a company willing to do this, at a cost I can afford, fine.
If not, I would like to undertake this project using the university's
facilities.  Here are the questions I have:

1. Is it feasible to plate onto an aluminized mylar surface?  I know that
it is possible to plate onto insulating surfaces *somehow*, so I would
assume that plating onto an aluminized surface would be easier from the
standpoint of conductivity.

2. Does anyone know where to get spherical aluminized mylar balloons in
the range of 750mm to 1m diameter?  (if the answer to the above question
is yes, of course)

3. Can anyone suggest any references on plating copper to a thickness of
1/8 to 1/4 inch?  References on strike-plating onto aluminized surfaces?

4. I assume it would be simpler to have some company finish the nickel
and chrome plating (I actually don't know if I need chrome, so long as
the nickel won't corrode I could just use nickel alone).  Is it practical
to do this type of plating myself using University resources, or would
it be easier to do this commercially?  The thickness does not matter;
the surface condition does.

	I will not be placing the hemispheres in SF6 (I can't afford it;
if air breakdown is a problem I may go for dehumidifying or for some
other, cheaper gas).

	Please respond to	bwhite@oucsace.cs.ohiou.edu

Thank you for your time.