[sci.electronics] Mercury and

peg@psuecl.bitnet (PAUL E. GANTER) (02/27/90)

In article <25E934B0.37FC@deimos.cis.ksu.edu>, mac@harris.cis.ksu.edu (Myron A. Calhoun) writes:
> Well, on a "real" (i.e., silver) dime mercury makes an amalgam with
> the silver and discolors the dime.  For more information on amalgams,
> ask your dentist the next time you see him/her.
>
> I don't know anything mercury would do anything to the current no-silver
> dimes, but if I had some mercury, I'd sure try it (after I got tired
> of pushing the little puddle around in my hand.  Would I wear a rubber
> glove?  Maybe.  But we didn't use to.  As someone once said, "Fools rush
> in where angels fear to tread".)
> --Myron.

Not sure about the new dimes, but GOLD reacts pretty much the same way,
apparently.  At a previous job, we used mercury probes to examine raw
semiconductor wafers.  A spot of liquid mercury makes contact with one
side of the wafer (the bare one), and a metal contact touches the gold-
coated side of the wafer.  (The gold is deposited in a vacuum chamber--
forget how thick it is...).  Anyway, if you get the mercury on the gold,
it very quickly removes it!

We tried this with various other materials in preparation to build our
own probe.  We went with aluminum as it appeared unaffected by mercury.

Just thought I'd throw that in....

Paul

forbes@aries.scs.uiuc.edu (Jeff Forbes) (02/27/90)

In article <89936@psuecl.bitnet> peg@psuecl.bitnet (PAUL E. GANTER) writes:
>
>Not sure about the new dimes, but GOLD reacts pretty much the same way,
>apparently.  At a previous job, we used mercury probes to examine raw
>semiconductor wafers.  A spot of liquid mercury makes contact with one
>side of the wafer (the bare one), and a metal contact touches the gold-
>coated side of the wafer.  (The gold is deposited in a vacuum chamber--
>forget how thick it is...).  Anyway, if you get the mercury on the gold,
>it very quickly removes it!
>
>We tried this with various other materials in preparation to build our
>own probe.  We went with aluminum as it appeared unaffected by mercury.
>
>Just thought I'd throw that in....
>
>Paul
>

The mercury cannot amalgamate the aluminum though the oxide coat. Aluminium
can be amalgamated with certain mercury salts which is useful if you want to
react the aluminum with something that cannot break through the oxide layer.


		Jeff

ornitz@kodak.UUCP (Barry Ornitz) (02/28/90)

In article <1990Feb27.055111.18154@ux1.cso.uiuc.edu> forbes@aries.scs.uiuc.edu 
(Jeff Forbes) writes:
>The mercury cannot amalgamate the aluminum though the oxide coat. Aluminium
>can be amalgamated with certain mercury salts which is useful if you want to
>react the aluminum with something that cannot break through the oxide layer.

Aluminum is fairly easy to amalgamate once you get through the oxide coating
found on any aluminum surface that has been exposed to air.  One simple way
is to place the mercury in the bottom of a small container and cover it with
hydrochloric acid.  Take the aluminum piece to be coated and immerse it in the
acid long enough for the oxide layer to be etched away; then immerse it into
the mercury below.  When the aluminum piece is removed, it should be coated
with a thin layer of mercury.

An interesting effect may be seen with aluminum amalgam.  The aluminum in the
surface of the amalgam will oxidize when exposed to air and slough off, but 
most of the mercury will remain and form new amalgam.  This will continue 
until either the mercury or the aluminum is consumed.  The aluminum oxide
formed will be a light, fluffy material.  If a piece of aluminum amalgam is
placed in a spot where air currents are negligible, the oxide can sometimes
form long, delicate "feathers".  It is dangerous to handle these, however,
because of the mercury content.

Remember that while metallic mercury not be very dangerous to handle, mercury
vapor is quite toxic.  The finer the droplets of mercury from a spill are, the
more surface area is exposed for vaporization.  The mercury left in the
"feathers" described above is extremely finely divided and thus quite 
hazardous.  If you spill mercury, dust the area with sulfur before trying to
vacuum it up.

BTW, we have EXTREME restrictions on mercury use at this plant.  Some of our
products go into film manufacturing and mercury is a silver halide poison.
We even restrict some cosmetics on employees that contain mercury compounds.
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gene@cooper.cooper.EDU (Gene (the Spook) ) (02/28/90)

in article <89936@psuecl.bitnet>, peg@psuecl.bitnet (PAUL E. GANTER) says:
>                              Anyway, if you get the mercury on the gold,
> it very quickly removes it!
> 
> We tried this with various other materials in preparation to build our
> own probe.  We went with aluminum as it appeared unaffected by mercury.
> 
> Just thought I'd throw that in....

Also, if you want a rather expensive but heatless desolderer, try a bit
of mercury as well.  We previously used solder as a means of sopping up
spilled mercury.  This way, you could scoop up some mushy glop instead of
chasing around teeny balls of pure mercury.  Loads of fun.

							Gene