[sci.electronics] Etching PCB's

johnh@macadam.mqcs.mq.oz.au (John Haddy) (03/18/91)

>I have also used ammonium persulfate (with a mercury chloride catalyst)
>as an etch.  It's only advantage is you can tell  how "used" the solution
>is as it turns blue from the dissolved copper sulfate.  The stuff is very
>poisonous (due to the catalyst) and should probably be avoided. 
>
Due to concerns here regarding our use of mercury chloride, we queried one of
the academics in the chemistry department. He replied with a list of other
suitable additives to our ammonium chloride - the most suitable of which was to
add a small quantity of phosphoric acid to the etch bath. Since we already use
this acid as a flux for some of the more "difficult" metals (steel, Nichrome
etc.), we had no problems purloining some for the etchant tank.

It's worth noting that ammonium persulphate needs to be heated in order for it
to work effectively as an etchant - another good reason to avoid mercuric
compounds (fumes etc.).

John Haddy

johnh@zubrette.mqcs.mq.oz.au	until the new domain names start working! :-)

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