[net.misc] Hydrogen

js2j@mhuxt.UUCP (sonntag) (03/25/85)

> > I saw a film somewhere (whose name I forget) about using hydrogen as
> > a fuel. It seems that John Q. Public isn't ready for it -- street
> > interviews showed that everybody thought of the Hindenburg.
> > Laura Creighton
> > utzoo!laura
> The Hindenburg used helium instead of hydrogen. Helium is 
> considerable more flammable. Germany had used it because
> there was an embargo of hydrogen against it.
> 					Bob Crowley
> 					ihlpm!crowley
     Wrong!  Helium is completely non-burnable, as its outer electron shell
is completely filled, it is a noble gas, extremely reluctant to combine 
with anything, under any circumstances.  As the Hindenburg blew up, it
must have been filled with something flammible, presumably hydrogen.
     As a way to verify this, the next time you see a kid with a helium
balloon, just poke it with a lit cigarette or a match, and observe that
while the balloon breaks, the gas inside doesn't ignite.  (But watch out
for your ankles, as some kids resent this type of experimenting.)
-- 
Jeff Sonntag
ihnp4!mhuxt!js2j
    "War is peace."-the ministry of truth

johnnyr@ihu1m.UUCP (John R. Rosenberg) (03/25/85)

> The Hindenburg used helium instead of hydrogen. Helium is 
> considerable more flammable. Germany had used it because
> there was an embargo of hydrogen against it.
> 
> 					Bob Crowley
> 					ihlpm!crowley
> 					Bell Labs-Naperville

*** REPLACE THIS LINE WITH YOUR DIRIGIBLE ***

Check your periodic table of the elements Bob. Helium is one of
the so-called Noble Gases. In other words is does not react
with any other elements (except under bizarre conditions of
temp. and pressure). Helium's one and only electron shell is full
of 2 electrons, the capacity of that shell. In other words there
is no way for other atoms to bond to it. Hence, it can NOT burn.
Since the Hindenburg burned, it was not filled with He. It was
in fact full of hydrogen.
 
John Rosenberg   ATT-NS
ihnp4!ihu1m!johnnyr

jhs@houxa.UUCP (J.SCHERER) (03/26/85)

> > I saw a film somewhere (whose name I forget) about using hydrogen as
> > a fuel. It seems that John Q. Public isn't ready for it -- street
> > interviews showed that everybody thought of the Hindenburg.
> > Laura Creighton
> > utzoo!laura
> The Hindenburg used helium instead of hydrogen. Helium is 
> considerable more flammable. Germany had used it because
> there was an embargo of hydrogen against it.
> 					Bob Crowley
> 					ihlpm!crowley
WRONG! (By exactly 180 degrees!)
The Hindenburg did use hydrogen which is flammable (and which mixed
with the proper amount of oxygen - or air - is extremely explosive).
Helium, which is inert, was not available to Germany because the
US (I think) had only recently discovered how to produce it in
quantity, was the sole source, and was somewhat reluctant to give
it to (prewar) Germany to power what could be used as a weapon.

On the subject of cars and peoples "irrational" fear of hydrogen:
gasoline leaks are not uncommon in today's cars - what would
happen with a hydrogen leak?  Could indeed be another Hindenburg.

  John Scherer  Bell Labs - Holmdel NJ

clewis@mnetor.UUCP (Chris Lewis) (03/27/85)

In article <643@houxa.UUCP> jhs@houxa.UUCP (J.SCHERER) writes:
>> > I saw a film somewhere (whose name I forget) about using hydrogen as
>> > a fuel. It seems that John Q. Public isn't ready for it -- street
>> > interviews showed that everybody thought of the Hindenburg.
>> > Laura Creighton
>> > utzoo!laura
>> The Hindenburg used helium instead of hydrogen. Helium is 
>> considerable more flammable. Germany had used it because
>> there was an embargo of hydrogen against it.
>> 					Bob Crowley
>> 					ihlpm!crowley
>WRONG! (By exactly 180 degrees!)
>....
>with the proper amount of oxygen - or air - is extremely explosive).
>Helium, which is inert, was not available to Germany because the
>US (I think) had only recently discovered how to produce it in
>quantity, was the sole source, and was somewhat reluctant to give
>it to (prewar) Germany to power what could be used as a weapon.
>
>On the subject of cars and peoples "irrational" fear of hydrogen:
>gasoline leaks are not uncommon in today's cars - what would
>happen with a hydrogen leak?  Could indeed be another Hindenburg.
>
>  John Scherer  Bell Labs - Holmdel NJ

John is correct, it was the US.  However, the US was stockpiling 
Helium for their own (probably military) purposes and there was 
very little of it available - not because of reluctance to give
war material to a possibly hostile Germany.  After all, it didn't
stop the US from selling scrap steel to Japan, or other strategic
material to Germany during the first part of WW II.

Germany was (understandably) very annoyed at the US for forcing 
them to use hydrogen for their civilian dirigibles (sp?).  
I think one source for this info is from the Nevil Shute book 
mentioned previously.  I believe that it was also mentioned as one 
of the reasons for Germany's attack on the US ship that caused
the US to enter WW I.

By the way, a company has started building dirigibles in Toronto
in the Wardair hanger at Toronto International Airport (whoops,
"Pearson International").  They have sold at least one (to the
US Navy).  Sure stops traffic on the 401 when they test one!
It's real neat to watch the thing just hang there, puttering
around.  Of course they are using helium.

Regarding "irrational fear of hydrogen" - there may be some truth
to it in automobiles.  It would be interesting to see some sort
of risk analysis of gasoline vs propane vs hydrogen.  There have
been a couple of propane car fires in Toronto recently.  Nobody 
killed, but several injured.  Hydrogen in a car would probably
be stored as a gas (isn't the pressure required to keep hydrogen
liquid too high to be practical in a car?  In contrast, propane is
very easy to keep liquid.)  The consequences of a leak are probably
somewhat more spectacular.
-- 
Chris Lewis, Motorola New Enterprises
UUCP: {allegra, linus, ihnp4}!utzoo!utcs!mnetor!clewis
BELL: (416)-475-1300 ext. 321

gwyn@brl-tgr.ARPA (Doug Gwyn <gwyn>) (03/28/85)

> > The Hindenburg used helium instead of hydrogen. Helium is 
> > considerable more flammable. Germany had used it because
> > there was an embargo of hydrogen against it.
> Since the Hindenburg burned, it was not filled with He. It was
> in fact full of hydrogen.

Yup, the original poster got the elements reversed.
Helium is also very rare and at the time the main source
was extraction from natural gas wells.  Another method
is air liquefaction.

mercury@ut-ngp.UUCP (Larry E. Baker) (03/28/85)

[]

> > I saw a film somewhere (whose name I forget) about using hydrogen as
> > a fuel. It seems that John Q. Public isn't ready for it -- street
> > interviews showed that everybody thought of the Hindenburg.
> > Laura Creighton
> > utzoo!laura
> The Hindenburg used helium instead of hydrogen. Helium is 
> considerable more flammable. Germany had used it because
> there was an embargo of hydrogen against it.
> 					Bob Crowley
>

If I remember my history trivia correctly, one of the reasons the
Hindenberg was on its way to the United States was because Hitler
wanted to convince the US to provide it with Helium, as the Zeppelin
was swiftly becoming an obsolite weapon due to the flammibility of its
*Hydrogen*.  They were, with the British incendary bullets, simply too
easy to shoot down.


-- 
-  Larry Baker @ The University of Texas at Austin
-  ...{seismo!ut-sally | decvax!allegra | tektronix!ihnp4}!ut-ngp!mercury

hutch@shark.UUCP (Stephen Hutchison) (03/29/85)

<Bug Bomb, contains explosive helium!>

In article <708@mhuxt.UUCP> js2j@mhuxt.UUCP (jeff sonntag) writes:
>> Quoting Bob Crowley
>> > quoting Laura Creighton
>> > I saw a film somewhere (whose name I forget) about using hydrogen as
>> > a fuel. It seems that John Q. Public isn't ready for it -- street
>> > interviews showed that everybody thought of the Hindenburg.
>> > Laura Creighton
>> > utzoo!laura
>> The Hindenburg used helium instead of hydrogen. Helium is 
>> considerable more flammable. Germany had used it because
>> there was an embargo of hydrogen against it.
>> 					Bob Crowley
>> 					ihlpm!crowley
>     Wrong!  Helium is completely non-burnable, as its outer electron shell
>is completely filled, it is a noble gas, extremely reluctant to combine 
>with anything, under any circumstances.  As the Hindenburg blew up, it
>must have been filled with something flammible, presumably hydrogen.

The Hindenburg was a hydrogen filled dirigible.  Helium was too expensive
to use for that purpose.  Hydrogen is plentiful, cheap, and Germany was
a major industrial power.  They MADE THEIR OWN hydrogen!  (Well, extracted
it, anyway.)  What kind of embargo could possibly succeed against a producer
of the prohibited substance?

Hutch

jlg@lanl.ARPA (03/30/85)

> The Hindenburg used helium instead of hydrogen. Helium is
> considerable more flammable. Germany had used it because
> there was an embargo of hydrogen against it.

You obviously have hydrogen and helium confused.  Hydrogen is the most
common element in the universe and chemically reacts with lots of stuff.
Helium is the second most common element in the universe but it is
chemically inert.  As a result, hydrogen is common on Earth but helium
doesn't combine with anything and, being lighter than air, escapes the
atmosphere if it is released into the environment.  The world's main source
of helium is the U.S. and we embargoed it as a military commodity in the
late thirties.  Since the Germans didn't have much helium, they used
hydrogen for their airships.

J. Giles

bnapl@burdvax.UUCP (03/30/85)

>> The Hindenburg used helium instead of hydrogen. Helium is 
>> considerable more flammable. Germany had used it because
>> there was an embargo of hydrogen against it.
>> 					Bob Crowley
>>

Come, come now.  A little high school chemistry, folks.  HYDROGEN, the
lightest element, is highly reactive in the presence of oxygen.  Remember
what happens when you combine some 'H's and some 'O's and a little heat.  You
get water and an explosion.  The Hindenburg was full of hydrogen, not
helium.  Helium is a non-flammable gaseous element.

-- 
Tom Albrecht 		Burroughs Corp.
			...{presby|psuvax1|sdcrdcf}!burdvax!bnapl

edward@ukma.UUCP (Edward C. Bennett) (03/31/85)

> The Hindenburg did use hydrogen which is flammable (and which mixed
> with the proper amount of oxygen - or air - is extremely explosive).
> Helium, which is inert, was not available to Germany because the
> US (I think) had only recently discovered how to produce it in
> quantity, was the sole source, and was somewhat reluctant to give
> it to (prewar) Germany to power what could be used as a weapon.
>
> John Scherer  Bell Labs - Holmdel NJ

One major point that nobody has mention yet is that Hydrogen
is lighter than Helium. So it provides more lift.

edward

	 {ucbvax,unmvax,boulder,research}!anlams! -|
		{mcvax!qtlon,vax135,mddc}!qusavx! -|-->	ukma!edward
			 {Lots of Places}!cbosgd! -|

swift@reed.UUCP (Theodore Swift) (03/31/85)

There is one big advantage of hydrogen over helium:  hydrogen
has a much greater "lifting power", four times as much according
to a book _Airships_ I read a long, long time ago. Four times
strikes me as off, since hydrogen, though of atomic weight 1.00X,
is diatomic.  Thus it would only have "twice" the lifting power.
This same _Airships_ book (sorry I don't remember the author/publ.)
stated that "helium was a biproduct of the American natural gas
industry, something Germany didn't have <natural gas>".  Whether or
not there was stockpiling or embargoing going on, I dunno.  
   As to hydrogen running cars, you wouldn't store the stuff as a
compressed gas or as a liquid; that'd still be too hairy if there
was an accident (and there would be, unless we drastically change
the basic natures of the maniacs we call drivers).  One way of
*safely* storing hydrogen that's being investigated is lithium
hydrides:  saturating lithium metal with hydrogen.  I saw an article
about a prototype VW van with LiH[n] cells on the floor in the back.
I think they were using heat from the exhaust to drive the hydrogen 
out of the lithium cells.  They had some kind of heating coils to get
things going in cold weather.  I can't say much more without going off
into speculation-land.

sph@bu-cs.UUCP (Scott P. Herzig) (03/31/85)

The Hindenberg was indeed filled with hydrogen.  The US, a major
producer of helium, was embargoing shipment of helium to Nazi
Germany.

sean@ukma.UUCP (Sean Casey) (04/01/85)

     Hydrogen is flammable?????? Wow! I swear  I  must  have
heard thus at least 30 times before!

     Look, folks. The average person on the net  is  not  so
stupid as to believe one man's bogus posting about the flam-
mability of helium/hydrogen. So if you MUST send flames then
PLEASE  send  to  to him personally, NOT to the net. You are
gaining nothing except enemies and  benefitting  no  one  by
posting  (1) The Obvious and (2) What has aleady been posted
30 times.

Sean (Phone Bills) Casey

-- 
Sean Casey	UUCP:				  {hasmed, cbosgd}-\
			{ucbvax, unmvax, boulder, research}!anlams---ukma!sean
				{mcvax!qtlon, vax135, mddc}!qusavx-/

		ARPA:	"ukma!sean"@ANL-MCS  or  sean%ukma.uucp@anl-mcs.arpa

doug@terak.UUCP (Doug Pardee) (04/01/85)

> I believe that it was also mentioned as one 
> of the reasons for Germany's attack on the US ship that caused
> the US to enter WW I.

Now how could the Germans have known in 1917 that in the '30s we were
going to develop a method of extracting helium, and that we would
embargo that technology?  And why would that serve as a reason to
sink a British ship?  The Lusitania was a British trans-Atlantic
passenger liner, owned by Cunard.  (If anyone's interested, the "ia"
at the end of the name was a hallmark of a Cunard ship, as the "ic"
at the end of the name was a hallmark of the rival White Star line).
-- 
Doug Pardee -- Terak Corp. -- !{hao,ihnp4,decvax}!noao!terak!doug

msb@lsuc.UUCP (Mark Brader) (04/03/85)

> There is one big advantage of hydrogen over helium:  hydrogen
> has a much greater "lifting power", four times as much according
> to a book _Airships_ I read a long, long time ago. Four times
> strikes me as off, since hydrogen, though of atomic weight 1.00X,
> is diatomic.  Thus it would only have "twice" the lifting power.

No, what it would have twice is the density.  The buoyancy is proportional
to the difference between the density of the gas and the density of air.
As I calculated in another article, the average molecular weight of air is
29.1; hydrogen is 2.0 and helium is 4.0.  And the density of a gas is
in direct proportion to the molecular weight.  So hydrogen is nowhere near
twice as buoyant as helium, but only 27.1/25.1 = about 1.08 times.

This is still enough to be significant in airship contexts, though.

(Another disadvantage of helium is that its tiny atoms leak through materials
that won't pass other gases.  I don't know how bad hydrogen is this way,
though, or how significant this effect is.)

Mark Brader

john@x.UUCP (John Woods) (04/03/85)

> liquid too high to be practical in a car?  In contrast, propane is
> very easy to keep liquid.)  The consequences of a leak are probably
> somewhat more spectacular.

Not necessarily.  Hydrogen is both highly volatile (as a liquid) and lighter
than air (as a gas).  It turns out that it doesn't hang around in flammable
concentrations for very long (unless you put a gasbag around it -- and if
you watch the film footage of the Hindenburg (which I did recently), the
hydrogen didn't burn very long--likely most of it just escaped).  Gasoline
(vapor) and propane, on the other hand, hang around in much higher
concentrations for greater lengths of time, hence they are easier to convince
to explode (and give you more time to do it).
-- 
John Woods, Charles River Data Systems, Framingham MA, (617) 626-1101
...!decvax!frog!john, ...!mit-eddie!jfw, jfw%mit-ccc@MIT-XX.ARPA

Think of it as "evolution inaction".

There are no unintentional spelling errors in this article.

clewis@mnetor.UUCP (Chris Lewis) (04/04/85)

In article <478@terak.UUCP> doug@terak.UUCP (Doug Pardee) writes:
>> I believe that it was also mentioned as one 
>> of the reasons for Germany's attack on the US ship that caused
>> the US to enter WW I.
>
>Now how could the Germans have known in 1917 that in the '30s we were
>going to develop a method of extracting helium, and that we would
>embargo that technology?  And why would that serve as a reason to
>Doug Pardee -- Terak Corp. -- !{hao,ihnp4,decvax}!noao!terak!doug

Whoops!  Musta gotten the wrong war or something.  I don't have a
copy of Shute's book handy (I *think* that's where I remember it
from).  Maybe the book suggested it as contributary to the German
declaration of war on the US for WWII.  Oh well, since I don't have
the quote handy, you might as well forget I said it.
-- 
Chris Lewis, Motorola New Enterprises
UUCP: {allegra, linus, ihnp4}!utzoo!utcs!mnetor!clewis
BELL: (416)-475-1300 ext. 321

swift@reed.UUCP (Theodore Swift) (04/07/85)

>Well, if Hitler wanted to convince the US, he sure did a good job,
>considering what happened to the Hindenburg in Lakewood, New Jersey.
>We didn't even have to use incenidary bullets, just a little St. Elmo's
>Fire.
>
>Sharon Badian  ihnp4!hocsp!ahutb!seb

I'm not sure, but I believe the cause of the Hindenburg disaster
has never been conclusively determined.  There have been many
explanations proposed, including the above theory of 
natural phenomenae, but there was also some evidence that there
was a saboteur who planted an incindiary bomb near the tail.  He
had intended it to go off AFTER the Hindenburg had moored and
all the passengers had disembarked (DeZeppelined? :-))
Does anyone else have more conclusive explanations, or any
confirmation of the saboteur theory?