[net.analog] thermal diodes

wolit@rabbit.UUCP (Jan Wolitzky) (10/23/84)

I'm not sure that "thermal diodes" is the correct term, but I recall
hearing a few years ago about the development of semiconductor devices
that acted as heat pumps or refrigerators.  Pass a current through
them and one end got hot, while the other got cold.  I think some
company actually tried marketing a portable refrigerator using these.
Does anybody know where I could get some specs on these devices, or
buy some of them?
-- 
Jan Wolitzky, AT&T Bell Laboratories, Murray Hill, NJ; (201) 582-2998

bottom@katadn.DEC (10/26/84)

 Cambion makes them. They are, if I remember right, called Thermonic devices.
We used them at the Pittsfield NH plant (cambion) to keep kapthon material
cool as it was being attached to IC sockets. They take a bit of current and
need to be heatsinked as the hot side gets quite hot. Cambion used to have
a applications manual. Good luck!

Dave Bottom Digital Equip Augusta, Me. (207)-623-6935 DNEAST::KATADN::BOTTOM

sleat@aat.UUCP (10/28/84)

[Apologies if this is a duplicate.  Local evidence suggests the first
posting never made it out of this system.]

>I'm not sure that "thermal diodes" is the correct term, but I recall
>hearing a few years ago about the development of semiconductor devices
>that acted as heat pumps or refrigerators.  Pass a current through
>them and one end got hot, while the other got cold.  I think some
>company actually tried marketing a portable refrigerator using these.
>Does anybody know where I could get some specs on these devices, or
>buy some of them?
>-- 
>Jan Wolitzky, AT&T Bell Laboratories, Murray Hill, NJ; (201) 582-2998



You might try:

	Cambridge Thermionic Corporation
	445 Concord Ave.
	Cambridge, MA  02238
	617-491-5400

I have an old data sheet (ca. 1979) for their model 801-1029-01-00-00
"Ceramic Module".  Basic spec's are:

	Max Temp Difference	>60degC
	Max Current		9 Amps
	Nominal Voltage		0.7Vdc
	Hot Side Temperature	50degC (max?)
	Max Heat Pumping Cap	>3.3 Watts
	Max operating Temp	125degC

The unit is a rectangular block approx .2 x .3 x 1 inches, with two
18awg pigtail leads.  Heat is transferred across the .2 inch dimension
(i.e., from one .3" x 1" surface to the other).

The energy transfer rate, at a fixed current, is of course inversely
proportional to the temperature difference.  The given transfer capacity
of 3.3 Watts is at 9 Amps with a delta-T of 0.  From the rather cryptic
performance curves given, it looks like you get about 0.2W across with
9 Amps at a delta-T of 50degC.  Below 5 Amps, transfer rate is approxi-
mately linear with current.  Above that it begins to fall off (as
resistance effects begin to dominate, I suspect), the slope reaching
zero at about 9 Amps.  Above 9 Amps, the slope goes negative.

Nowhere on the data sheet does it mention that this is a semiconductor
device, though the leads are color coded for polarity and the 0.7V
suggests a semiconductor junction breakdown voltage.  I believe that
this exploits a phenomenon other than the Peltier effect, though my
recollection on such matters is hazy at best.  Any denizens of
net.physics care to elucidate?

Michael Sleator
Ann Arbor Terminals
{aatpdx, cbosgd, mb2c, psu-cs, uofm-cv}!aat!sleat

scott@wuphys.UUCP (Scott Barthelmy) (10/29/84)

[]
A better name for these devices is "thermoelectric coolers" or more
technically they work on the principle of the "Peltier effect".
When an electric current flows across a junction of dissimilar
materials heat is absorbed or released.  The heat flow is a result of
the different "electronic" heat capacities of the materials.
The opposite of a thermocouple device.  See also Seebeck and Thompson
effects.

The formula is:		Q = pi * I
where 'pi' (the Peltier coefficient) is of order
	0.003 for metals
	0.03 for highly doped semiconductors
	0.3 for lightly doped semiconductors
In practical units:
	2 BTU/hour ~= 1 Volt*Amp*hour
Junction temperature differentials can get up to 50 degrees centigrade.

For a supplier of these devices, try:
	MELCOR (Materials Electronics Products Corp)
	990 Spruce St
	Trenton, New Jersy  08648
(I am looking at their 1981 catalog so bewarned of changes.)
There must be other suppliers; try EEM.

These things have been aailable on the consumer product market for
awhile.  My parents had one of these "electronic ice chests" back
in 1978.  The ice chest was 3cuft and would keep a full load at ~40
using about 4-5 amps at 12 volts.  The coooling unit was about 4"x4"x1".
It could counter balance heat inflow through the chest insolation,
but was terrible if you put a freashly roasted turkey in it.

These devices can be used to heat things as well as cool.
Simple joule heating is about 50% more efficent.

Scott Barthelmy		ihnp4!wuphys!scott
"I am a child of the unixverse."

jeffw@tekecs.UUCP (Jeff Winslow) (11/01/84)

I could reply to this by mail, but this newsgroup doesn't get enough
activity (only 30 articles here!) so -----

I think what you are talking about is called a thermoelectric refrigerator,
based on the Peltier effect. If you put current through a junction of 
certain dissimilar metals or semiconductors (say bismuth and tellurium), 
the junction area gets cold. 

I think there are some beer-cooler type things to run off of a car battery
that use this principle.

One vendor of thermoelectric modules is Cambion, 1 Alewife Place, Cambridge,
MA (02140). I can't speak for or against them, as I just happened to get a
catalog of theirs, but it's a start.

					     Jeff Winslow
		       			Switching supply designer

				An analog man in a digital world...

wls@astrovax.UUCP (William L. Sebok) (11/02/84)

The CCD (charge-coupled device) light detectors on the Wide-angle camera of the
space telescope will be cooled with such thermo-electric devices. There the
vacuum of space helps quite a bit in the thermal insulation.
-- 
Bill Sebok			Princeton University, Astrophysics
{allegra,akgua,burl,cbosgd,decvax,ihnp4,noao,princeton,vax135}!astrovax!wls