[net.physics] Thermo and prob :Schools of thought

stekas@hou2g.UUCP (J.STEKAS) (03/24/84)

Thermodynamics is certainly true, rigorously.  But what thermo
doesn't give you is a physical definition of entropy.  So maybe
a third school of thought is that thermodynamics is just a para-
meterization without statistical mechanics to define the entropy.

                                                Jim

Shinbrot.WBST@Xerox.ARPA (04/16/84)

re: "Thermodynamics is certainly true, rigorously...."

I think some common sense should be thrown into this fray.  I say
thermodynamics is rigorously untrue.  This is so because the subject is
not restricted to thermoSTATICS, as it ought to be.  Quasi-statics
(remember thermo. 101?) , while perhaps necessary to achieving
comprehensible results, are misleading in that the results are seldom
CORRECT ones.  If anyone doubts this, I give you the internal combustion
engine, and challenge the reader to show me how more than 10-fold
volume, pressure, and temperature increases within, typically, 1 to 5
milliseconds can possibly be termed quasi-static.  External combustion
engines, Stirling engines, and other text-book examples are likewise not
correctly, nor even approximately, described by thermostatics.  

The fact that we speak of thermodynamics as a correct science shows how
easily we can mislead ourselves into accepting fallacious axioms when it
seems convenient to do so.  Few idealized problems, and almost no real
world ones are quasi-static, and those that are are singularly
uninteresting.  

Contrarily yours,

Troy Shinbrot